高等学校化学学报

高等学校化学学报 ›› 1998, Vol. 19 ›› Issue (S1): 54.

• Organic Synthesis Chemistry • 上一篇    下一篇

Synthesis and Characterization of Macrocycles Containing 1,3,4-Oxadiazole

Wenting Hua, Shu Wang   

  1. Department of Chemistry, Peking University, Beijing 100871
  • 出版日期:1998-12-31 发布日期:1998-12-31

Synthesis and Characterization of Macrocycles Containing 1,3,4-Oxadiazole

Wenting Hua, Shu Wang   

  1. Department of Chemistry, Peking University, Beijing 100871
  • Online:1998-12-31 Published:1998-12-31

PDF (PC)

摘要： The design of molecules with delocalized π-electronic structures which are useful as organic conductor and light-emitting diodes(LEDs) has attracted much attention.[1-2] We have synthesized some conjugated Schiff base macrocycles containing 1,3,4-oxadiazole(such as compound 1) and after being doped with I2,they showed electrical conductivity in the region of semiconductor.[3] To continue this work and understand the relationship between molecular structure and solid state properties, we designed other conjugated schiff base macrocycle containing 1,3,4-oxadiazole.

Abstract: The design of molecules with delocalized π-electronic structures which are useful as organic conductor and light-emitting diodes(LEDs) has attracted much attention.[1-2] We have synthesized some conjugated Schiff base macrocycles containing 1,3,4-oxadiazole(such as compound 1) and after being doped with I2,they showed electrical conductivity in the region of semiconductor.[3] To continue this work and understand the relationship between molecular structure and solid state properties, we designed other conjugated schiff base macrocycle containing 1,3,4-oxadiazole.

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