A Study of the Ternary System of Zn(ClO4)2-BAPHDCA-H2O at 30℃ and the Preparation and Characterization of the Zn(BAPHDCA)(ClO4)2·2H2O

Abstract

Abstract: The solubilities and the refractive indexes of the saturated solutions of the titled system at 30 ℃ have been studied and the corresponding equilibrium diagram and refractive index diagram were constructed, both solubility curves and refractive index curves of the system consist of three branches, corresponding to BAPHDCA, Zn(BAPHDCA)(ClO₄)₂·2H₂O and Zn(ClO₄)₂·6H₂O, respectively. The Zn(BAPHDCA)(ClO₄)₂·2H₂O is a new compound, which was characterized by chemical and elemental analysis, IRspectra and thermoanalysis.

Key words: Phase equilibrium, Ternary system, N,N′-Bis(antipyrine-4′-yl)-hexanedicarboxamide, Perchlorate zinc

CLC Number:

O642.42

TrendMD:

CUI Bin, TANG Zong-Xun, GUO Zhi-Zhen, CHEN Kai-Xun. A Study of the Ternary System of Zn(ClO₄)₂-BAPHDCA-H₂O at 30℃ and the Preparation and Characterization of the Zn(BAPHDCA)(ClO₄)₂·2H₂O[J]. Chem. J. Chinese Universities, 1998, 19(8): 1208.

[1]	OUYANG Shunli, ZHANG Mingzhe, ZHANG Yongzhao, HU Qingcheng, WEI Haiyan, WU Nannan, HUANG Baokun. Raman Spectroscopic Investigation on the Effect of Hydrogen Bond on Molecular Structure in Ternary Aqueous Solution^† [J]. Chem. J. Chinese Universities, 2018, 39(4): 758.
[2]	WANG Lin*, LUO Jian-Cheng, LI Ru-Lin, CHEN Kai-Xun. High Pressure Phase Equilibrium Model of 2-Butanol in CO2 [J]. Chem. J. Chinese Universities, 2010, 31(7): 1416.
[3]	WANG Lin, LI Ru-Lin, SUN Lin-Tao , CHEN Kai-Xun*. Studies on Phase Equilibrium of Tertbutanol in Supercritical CO₂ [J]. Chem. J. Chinese Universities, 2009, 30(8): 1631.
[4]	ZHENG Zhi-Yuan¹, ZENG Ying¹*, CHEN Jun², LIN Xiao-Feng¹. Experimental Study on the Metastable Phase Equilibria of the Quaternary System Na₂CO₃-Na₂SO₄-Na₂B₄O₇-H₂O at 273 K [J]. Chem. J. Chinese Universities, 2008, 29(2): 336.
[5]	HUANG Xue-Li*, MA Feng-Yun, SUN Hong-Mei. Liquid-solid Phase Equilibrium for the Quinary System Na⁺, Mg²⁺//Cl^-, SO₄^2-, NO₃^-, H₂O Saturated with NaCl at 298.16 K [J]. Chem. J. Chinese Universities, 2008, 29(2): 360.
[6]	ZHAO Xue-Feng, CHEN Li, TIAN Yi-Ling, ZHANG Feng-Cai, XUE Yuan . High Pressure Vapour-liquid Equilibrium of Supercritical Carbon Dioxide+Diethyl Carbonate System [J]. Chem. J. Chinese Universities, 2004, 25(7): 1298.
[7]	ZHANG Jing-Chang, ZHANG Jian-Jun, LIU Wei-Wei, CAO Wei-Liang . Studies on Relationship Between Temperature and Pressure of the Supercritical CO₂+EtOH+CO+H₂ Quaternary System and Its Super-critical Properties [J]. Chem. J. Chinese Universities, 2004, 25(2): 330.
[8]	ZENG Ying, YIN Hui-An, TANG Ming-Lin, FENG Xiao-Xiang . A Study of the Phase Equilibrium for Quinary System Li⁺, Na⁺, K⁺//CO₃^2-, Cl^--H₂O at 298.15 K [J]. Chem. J. Chinese Universities, 2003, 24(6): 968.
[9]	ZHANG Feng-Xing, WEI Xiao-Lan, LI Jun. Studies on the Isothermal Solubility for Quinary System K₂²⁺,Mg²⁺//Cl₂^2-,SO₄^2--CO(NH₂)₂-H₂O and Its Boundary System MgSO₄-MgCl₂-CO(NH₂)₂-H₂O at 25℃ [J]. Chem. J. Chinese Universities, 2003, 24(5): 757.
[10]	GAO Sheng-Li, YANG Xu-Wu, CHEN San-Ping, LI Huan-Yong, SHI Qi-Zhen . Synthesis, Properties and Phase Equilibrium of Zn(NO₃)₂-Leu-H₂O System(25 ℃) [J]. Chem. J. Chinese Universities, 2003, 24(2): 195.
[11]	ZHU Hu-Gang, TIAN Yi-Ling, CHEN Li, FENG Ji-Jun, FU Hua-Feng . Studies on Vapor-liquid Phase Equilibria for SCF CO₂+CH₃OH and SCF CO₂+C₂H₅OH Systems [J]. Chem. J. Chinese Universities, 2002, 23(8): 1588.
[12]	ZHANG Feng-Xing, YANG Qin, LI Jun, WANG Zhen-Jun, LI Heng-Xin . Studies on the Polythermal Solubility of System Na₂B₄O₇- Na₂CO₃-NaHCO₃-NaBO₂-H₂O at₀-45 ℃ [J]. Chem. J. Chinese Universities, 2002, 23(7): 1236.
[13]	HU Man-Cheng, MENG Mei, GAO Shi-Yang, LIU Zhi-Hong, XIA Shu-Ping . Studies on the Phase Diagram of CsCl-C₂H₅OH-H₂O Ternary System at 30, 40 and 50℃ [J]. Chem. J. Chinese Universities, 2002, 23(7): 1219.
[14]	JIN Zuo-Mei, ZHOU Hui-Nan, WANG Li-Sheng. Studies on the Metastable Phase Equilibrium of Na⁺, K⁺,Mg⁺ //Cl^-, SO₄^2--H₂O Quinary System at 15℃ [J]. Chem. J. Chinese Universities, 2002, 23(4): 690.
[15]	JIN Zuo-Mei, ZHOU Hui-Nan, WANG Li-Sheng . Studies on the Metastable Phase Equilibrium of Na⁺, K⁺, Mg^²⁺ ∥Cl^-, SO₄^2--H₂O Quinary System at₃₅ ℃ [J]. Chem. J. Chinese Universities, 2001, 22(4): 634.

A Study of the Ternary System of Zn(ClO₄)₂-BAPHDCA-H₂O at 30℃ and the Preparation and Characterization of the Zn(BAPHDCA)(ClO₄)₂·2H₂O

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments