Synthesis and Fluorescent Properties of Dendrimer PAMAM(1G)-FCD

Chem. J. Chinese Universities

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Synthesis and Fluorescent Properties of Dendrimer PAMAM(1G)-FCD

HAN Qiao-Rong^1,2, WANG Bing-Xiang², HE Xu-Min^1*, DING Ma-Tai¹, XIA Hai-Ping¹

1. College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China;
2. College of Chemistry and Environment Science, Nanjing Normal University, Nanjing 210097, China

Received:2008-05-22 Revised:1900-01-01 Online:2009-03-10 Published:2009-03-10
Contact: HE Xu-Min

Abstract

Abstract: A dendrimer of PAMAM(1G)-FCD was synthesized. Its structure was characterized via IR, ¹H NMR, MALDI-TOF-MS, etc. The fluorescent properties of PAMAM(1G)-FCD, as well as the influence of Sn²⁺ on this dendrimer, were also studied systematically. The results show that the fluorescence of this dendrimer can be significantly enhanced by Sn²⁺. The UV spectra detected a new absorption peak at 360 nm with the addition of Sn²⁺ into the solution of PAMAM(1G)-FCD, suggesting that chemical reaction occured in the Sn²⁺ and PAMAM(1G)-FCD system. This hybrid material of metal-dendrimer holds promise as a scarce material to emit blue fluorescence.

Key words: Dendrimer PAMAM, 2-Fluorenecarboxaldehyde, Sn²⁺ ion, Fluorescent property

CLC Number:

O631

TrendMD:

HAN Qiao-Rong^1,2, WANG Bing-Xiang², HE Xu-Min^1*, DING Ma-Tai¹, XIA Hai-Ping¹. Synthesis and Fluorescent Properties of Dendrimer PAMAM(1G)-FCD[J]. Chem. J. Chinese Universities, doi: .

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Synthesis and Fluorescent Properties of Dendrimer PAMAM(1G)-FCD

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