Effect of Surfactants on the Electrooxidation of 3-Picoline to Nicotinic Acid

Chem. J. Chinese Universities

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Effect of Surfactants on the Electrooxidation of 3-Picoline to Nicotinic Acid

GAO Yang-Yan¹, LI Ke-Chang¹, GU Qiang¹, CHEN Xiao-Dong², ZHANG Heng-Bin¹, ZHANG Yu-Min^1*

1. College of Chemistry, Jilin University, Changchun 130012, China;
2. Experimental Center of Testing Science, Jilin University, Changchun 130023, China

Received:2008-04-11 Revised:1900-01-01 Online:2009-02-10 Published:2009-02-10
Contact: ZHANG Yu-Min

Abstract

Abstract: The effects of surfactants with different concentrations on the electrooxidation of 3-picoline were extensively investigated via the cyclic voltammetry curves. The results indicate that the current density are evidently enhanced in electrooxidation with cetyltrimethyl ammonium bromide, sodium fatty alcohol ether sulfate, sodium dodecyl benzene sulfonate, N,N-dimethyl-N-dodecyl acetate sodium and sorbitan monostearate. So, it is probably synthesized nicotinic acid from 3-picoline in the lower concentration sulfuric acid with surfactants. The product selectivity and the current efficiency under the specific conditions are enhanced than no surfactants in the electrolyte.

Key words: Surfactants, Cyclic voltammetry curves, Nicotinic acid, 3-Picoline, Electrooxidation

CLC Number:

O646.5

TrendMD:

GAO Yang-Yan¹, LI Ke-Chang¹, GU Qiang¹, CHEN Xiao-Dong², ZHANG Heng-Bin¹, ZHANG Yu-Min^1*. Effect of Surfactants on the Electrooxidation of 3-Picoline to Nicotinic Acid[J]. Chem. J. Chinese Universities, doi: .

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Effect of Surfactants on the Electrooxidation of 3-Picoline to Nicotinic Acid

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