Chem. J. Chinese Universities

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Synthesis of Zeolite ECR-1 from Hydrothermal Phase Transition of Zeolite Y

DING Hong, SONG Jiang-Wei, REN Li-Min, XIAO Feng-Shou*   

  1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, China
  • Received:2008-10-28 Revised:1900-01-01 Online:2009-02-10 Published:2009-02-10
  • Contact: XIAO Feng-Shou

Abstract: Aluminosilicate zeolite ECR-1 was successfully obtained under hydrothermal condition at 100 ℃ by hydrothermal phase transition of zeolite Y in the absence of organic template. When n(Na2O)/n(SiO2) ratio in the starting aluminosilicate gel[n(SiO2)∶n(Al2O3)∶n(Na2O)∶n(H2O)=10∶1.0∶2.5—3.3∶200] was 0.33, the phase transition from zeolite Y to zeolite P occurred. However, when the n(Na2O)/n(SiO2) ratio was 0.25, zeolite Y was converted into zeolite ECR-1. In this case, zeolite Y was served as nutrient for the crystallization of zeolite ECR-1.

Key words: Organic-template free, Phase transition, Hydrothermal condition, Zeolite ECR-1, Zeolite Y

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