Chem. J. Chinese Universities ›› 1983, Vol. 4 ›› Issue (3): 359.

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A STUDY OF KINETICS AND MECHANISM OF HOMOGENEOUS CATALYTIC HYDROCHLO- RINATION OF ACETYLENE

Chen Rongti( Y. T. Chen), Zhang Qiyan, Wang Wande   

  1. Department of Chemistry, N ankai University, Tianjin
  • Received:1981-12-16 Online:1983-06-24 Published:1983-06-24

Abstract: The kinetics of the reaction of acetylene hydrochlorination in hydrochloric acid with mercuric chloride(HgCl2)as catalyst has been studied. The results showed that rate equation could be expressed by r = k'[HgCl2][H+]3[CH = CH],and the apparent energy of activation obtained is E = 13.6Kcal/mol. Areaction mechanism was proposed.

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