Studies on the Thermodynamic Properties of Adduction Reaction between Ni[(C8H17O)2PS2]2 and Aldehydes by GLC Method

Chem. J. Chinese Universities ›› 1990, Vol. 11 ›› Issue (5): 551.

• Articles • Previous Articles

Studies on the Thermodynamic Properties of Adduction Reaction between Ni[(C₈H₁₇O)₂PS₂]₂ and Aldehydes by GLC Method

Yu Yunpeng¹, Zhu Duolin¹, Xu Zheng², Lin Jianhua², You Xiaozeng²

1. Department of Chemistry, Zhenjiang Teachers'College, Zhenjiang;
2. Coordination Chemistry Institute, Naijang University, Nanjing

Received:1988-08-27 Online:1990-05-24 Published:1990-05-24

Abstract

Abstract: The thermodynamic properties of adduction reaction of Ni[(C₈H₁₇O)₂PS₂]₂ and CH₃CHO, C₂H₅CHO, n-C₃H₇CHO and n-C₄H₉CHO were studied by GLC method. The equilibrium constants were determined between 333～363K and described by the emperical equation: 1gK = - 0.2087 - 0. 9209 N_c + (291. 9 + 265. 1 N_c)/T ΔH and ΔS were calculated by the least square method. It was found that - ΔH and - ΔS increased linearly with the increase of number of carbon in aldehydes: -ΔH=5. 59 + 5. 08 N_c (kJ/mol), -ΔS=3. 39 + 17. 63 N_c(J/K ·mol). The nature of adduct bonds was explained by electro-static model.

Key words: Gas-liquid chromatography, Dialkyldithiophosphate, Aldehydes, Thermodynamic parameters

TrendMD:

Yu Yunpeng, Zhu Duolin, Xu Zheng, Lin Jianhua, You Xiaozeng. Studies on the Thermodynamic Properties of Adduction Reaction between Ni[(C₈H₁₇O)₂PS₂]₂ and Aldehydes by GLC Method[J]. Chem. J. Chinese Universities, 1990, 11(5): 551.

[1]	WANG Ruxin, ZHAO Zhongjun, HE Feiyao, YUE Hanlu, DENG Fulong, LI Hong, LI Wenwen, DUAN Yixiang. Characteristic Analysis of C₁—C₃n-Aldehydes and n-Alcohols in Proton Transfer Reaction Time-of-flight Mass Spectrometry [J]. Chem. J. Chinese Universities, 2021, 42(12): 3632.
[2]	WANG Yan-Mei, CAI Shu-Lan, HE Lin-Xin, ZHU Sha-Sha, WANG Jun, LIN Xiao, LI Yu-Long, ZOU Li-Ke. Crystal Structure, Spectroscopic Properties and Antibacterial Activity of Binuclear Lead Complex with O, O'-Di(p-methylphenyl)dithiophosphate [J]. Chem. J. Chinese Universities, 2013, 34(1): 30.
[3]	WANG Zhao-Shen, LIU Chen-Jiang. LiNH₂SO₃ Promoted Synthesis of 1,8-Dioxo-octahydroxanthene Under Solvent-free Conditions [J]. Chem. J. Chinese Universities, 2012, 33(03): 507.
[4]	WEI Rong-Bao*, LIANG Ya. Solvent-free Synthesis of 4,6,10,12,16,18,22,24-Octa-hydroxy-2,8,14,20-tetra{(tri-(3-phenyl-2,4,8,10-tetraoxaspiro[5.5]undecyl))-(4-(2-(4,6,10,12,16,18,22,24-octa-hydroxy)Calixresorcinarenyl)phenyl)}calixresorcinarene Spiro macromolecul [J]. Chem. J. Chinese Universities, 2008, 29(2): 309.
[5]	LIU Wei-Wei, OU Song, WANG Bing-Xiang, HU Hong-Wen. Reaction of 3-Thioformylindolizine(Thioaldehyde) with 1,2-and 1,4-Dimethylpyridinium Iodides [J]. Chem. J. Chinese Universities, 2004, 25(4): 667.
[6]	AI Lin, LIU Qun, LI Xiao-Fang, WANG Mang . Studies on the Condensation Reaction of α,α-Diacetyl Ketene Dithioacetals with Arylaldehydes [J]. Chem. J. Chinese Universities, 2003, 24(7): 1222.
[7]	JIANG Yu-Cheng, WANG Jian-Ji, ZHUO Ke-Lei, GAO Shi-Yang, XIA Shu-Ping, HU Man-Cheng . Thermodynamic Parameters of Interaction of CsCl with D-Glucose, D-Fructose and D-Sucrose in Water at 298.15K [J]. Chem. J. Chinese Universities, 2003, 24(10): 1842.
[8]	LI Ting-You, WANG Li-Ping, ZHANG Tao, LI Yao-Xian, WANG Zong-Mu. Studies on the Stereoselectivity of Pinacol Coupling Reaction Mediated by TiCl₄-Mg [J]. Chem. J. Chinese Universities, 2000, 21(9): 1391.
[9]	YANG Da-Cheng, ZHANG Guo-Lin, YANG Yu, ZHONG Yu-Guo . The Mannich Reaction of 4-Methylacetophenone with Aromatic Aldehydes and Aromatic Amines [J]. Chem. J. Chinese Universities, 2000, 21(11): 1694.
[10]	XIE Bin, WU Shi-Ye . Synthesis and Characterization of (5,7,7,12,14,14-Hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-dieno)Nickel Bis(O,O'-dialkyldithiophosphate) [J]. Chem. J. Chinese Universities, 1998, 19(1): 74.
[11]	ZHOU Xiao-Xian, WANG Yi-Lin, LI Song-Lin, ZHENG Guo-Kang. Studies on Self-Association of n-AlcohoIs by Gas-Liquid Chromatography [J]. Chem. J. Chinese Universities, 1993, 14(6): 817.
[12]	Bai Tongchun, Lu Jinsuo, Zhou Xishun . Studies on Salt Effect in Solution by Gas-Liquid Chromatdgrapby [J]. Chem. J. Chinese Universities, 1990, 11(8): 859.
[13]	Liu Shixiong, Lin Xichang, Xu Zheng, Lin Jianhua, Yu Yunpeng, You Xiaozeng. Determination of Equilibrium Constants for the Adductive Reaction of Bis-(O,O'-Dicyclohexyl-Dithiophosphato) Nickel(Ⅱ) with Pyridine and the Crystal Structure of Ni[(C₆H₁₁O)₂PS₂]₂·2Py [J]. Chem. J. Chinese Universities, 1989, 10(12): 1225.

Studies on the Thermodynamic Properties of Adduction Reaction between Ni[(C₈H₁₇O)₂PS₂]₂ and Aldehydes by GLC Method

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 13

Recommended Articles

Metrics

Comments