Biomolecule-assisted Solvothermal Synthesis of Sb2S3 Nanorods

Chem. J. Chinese Universities ›› 2010, Vol. 31 ›› Issue (7): 1303.

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Biomolecule-assisted Solvothermal Synthesis of Sb₂S₃ Nanorods

ZHONG Jia-Song¹, XIANG Wei-Dong^1,2*, LIU Li-Jun¹, YANG Xin-Yu¹, CAI Wen², ZHANG Jing-Feng¹, LIANG Xiao-Juan¹

1. College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325035, China;
2. College of Materials Science and Engineering, Tongji University, Shanghai 200092, China

Received:2009-11-16 Online:2010-07-10 Published:2010-07-10
Contact: XIANG Wei-Dong. E-mail: weidongxiang@yahoo.com.cn
Supported by:
国家自然科学基金(批准号: 50772075, 50972107)资助.

Abstract

Abstract:

A simple biomolecule-assisted synthetic route has been successfully developed to prepare antimony sulfide(Sb₂S₃) nanorods at 170 ℃ for 12 h. In this synthetic system, antimony chloride(SbCl₃) is employed to supply antimony source and L-cystine is used as sulfide source. X-ray powder diffraction(XRD), energy dispersion spectroscopy(EDS) and X-ray photoelectron spectroscopy(XPS) results indicate that the as-prepared powder is pure orthorhombic Sb₂S₃. Field-emission scanning electron microscopy(FESEM) and transmission electron microscopy(TEM) show that the Sb₂S₃ nanorods have an average diameter of 150 nm and length ranging from 3 to 6 μm. The effect of reaction time on morphology of the product has been investigated, and a possible formation mechanism for the antimony sulfide nanorods was also discussed.

Key words: Antimony sulfide; Solvothermal; Nanorod; L-cystine; Biomolecule

TrendMD:

ZHONG Jia-Song, XIANG Wei-Dong*, LIU Li-Jun, YANG Xin-Yu, CAI Wen, .... Biomolecule-assisted Solvothermal Synthesis of Sb₂S₃ Nanorods[J]. Chem. J. Chinese Universities, 2010, 31(7): 1303.

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Biomolecule-assisted Solvothermal Synthesis of Sb₂S₃ Nanorods

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