Chem. J. Chinese Universities ›› 2010, Vol. 31 ›› Issue (6): 1179.

• Articles • Previous Articles     Next Articles

Synthesis of Fluoroalkyl Substituted Biphenol A Derivatives

TANG Ting1, YANG Xue-Yan2, CHEN Xi2, WU Fan-Hong2,3*   

  1. 1. Pharmaceutical Sciences Department, Medicine and Health Manage College, Hangzhou Normal University, Hangzhou 310036, China;
    2. School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237, China;
    3. Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China
  • Received:2009-06-23 Online:2010-06-10 Published:2010-06-10
  • Contact: WU Fan-Hong. E-mail: wfh@ecust.edu.cn
  • Supported by:

    国家自然科学基金(批准号: 20672034)资助.

Abstract:

Synthesis of new biphenol A derivatives are significant due to their utility as monomers. In this paper, the fluoroalkylation of phenol derivatives initiated by sodium dithionite in the presence of CTMAB as phase catalyst was investigated to give fluoralkyl phenols. When biphenol A was used as the substrate, some new biphenol A derivatives was obtained. Mono-, di- or tetra-fluoroalky subtstitued biphenol A derivatives, which may be important monomers, were prepared when different molar ratio of fluoroalkyl iodides and biphenol A was employed.

Key words: Fluoroalkylation; Biphenol A; Phenol derivative

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