Electric-sensitive Properties and Mechanism of P(AMPS-co-BMA) Hydrogels

Chem. J. Chinese Universities ›› 2010, Vol. 31 ›› Issue (2): 406.

• Articles • Previous Articles Next Articles

Electric-sensitive Properties and Mechanism of P(AMPS-co-BMA) Hydrogels

LIN Song-Bai^1,2*, YUAN Cong-Hui¹, ZHANG Xian¹, HUANG Bo-Yang¹

1. College of Material Science & Engineering, Huaqiao University, Quanzhou 362021, China;
2. Liming Vocational University, Quanzhou 362000, China

Received:2009-04-23 Online:2010-02-10 Published:2010-02-10
Contact: LIN Song-Bai. E-mail: sblin@hqu.edu.cn; lsb@lmu.edu.cn
Supported by:
泉州市优秀人才培养专项基金(批准号: 08A01)和福建省自然科学基金(批准号: E0510024)资助.

Abstract

Abstract:

Electric-sensitive hydrogels[P(AMPS-co-BMA)] were prepared by free-radical polymerization with 2-acrylamido-2-methyl propyl sulfonic acid(AMPS) as ionic monomer and (BMA) as non-ionic monomer, using N,N′-methylene bisacrylamide as crosslinking agent, azobisisobutyronitrile as initiator and N,N-dimethyl formamide as solvent, respectively. The swelling properties of hydrogels in deionized water and in NaCl solution were studied in detail. The results show that the swelling rate of the hydrogels increases with the increasing content of AMPS, and the equilibrium swelling ratio of the hydrogels ranges from 236.4 to 298.5. In addition both the deswelling speed and the deswelling extent of the hydrogels decrease with the increasing concentration of polyion in inside of the hydrogels. Moreover, the electrical sensitivity of the hydrogels was studied. The swelling properties of the hydrogels in NaCl solution with an applied voltage were related to the ionic concentration difference between interior hydrogels and exterior NaCl solution. When the concentration of polyion in interior hydrogels is higher than the concentration of NaCl in solution, the hydrogels swells; contrarily, the hydrogels deswells. The bending direction of the hydrogels was also related to the ionic concentration difference between interior hydrogels and exterior NaCl solution. When the concentration of polyion in interior hydrogels is higher than the concentration of NaCl in solution, the hydrogels bend toward cathode; contrarily, the hydrogels bend toward anode. Further investigation shows that the bending speed of the hydrogels also depends on the temperature significantly.

Key words: Hydrogel; Electrical sensitivity; Poly(2-acrylamido-2-methyl propyl sulfonic acid-co-butylacrylate)

TrendMD:

LIN Song-Bai*, YUAN Cong-Hui, ZHANG Xian, HUANG Bo-Yang. Electric-sensitive Properties and Mechanism of P(AMPS-co-BMA) Hydrogels[J]. Chem. J. Chinese Universities, 2010, 31(2): 406.

References

[1]Sen M., Güven O.. Radiation Physics and Chemistry[J], 1999, 55: 113—120
[2]Hamlen R. P., Kent C. E., Shafer S. N.. Nature[J], 1965, 206: 1149—1150
[3]Tanaka T., Nishio I., Sund S., et al.. Science[J], 1982, 218: 467—469
[4]Shiga T., Kurauchi T.. J. Appl. Polym. Sci.[J], 1990, 39: 2305—2320
[5]Osada Y., Okuzaki H., Hori H.. Nature[J], 1992, 355: 242—244
[6]Irie M., Kunwatchakun D.. Macromolecules[J], 1986, 19: 2476—2477
[7]Hirotsu S.. Jpn. J. Appl. Phys.[J], 1985, 24: 396—398
[8]LIU Gen-Qi(刘根起), ZHAO Xiao-Peng(赵晓鹏), JING Wei-Wei(靖伟伟), et al.. Chinese Journal of Materials Research(材料研究学报)[J], 2006, 20(5): 479—484
[9]Lira L. M., de Torresi S. I. C.. Electrochem. Commun.[J], 2005, 7: 717—723
[10]Supranee K., Siridech B.. European Polymer Journal[J], 2006, 42: 1609—1616
[11]Hudson S. M., Gil E. S.. Prog. Polym. Sci.[J], 2004, 29: 1173—1222
[12]Galaev I. Y., Mattiasson B.. Trends Biotechnol.[J], 1999, 17: 335—340
[13]Jeong B., Gutowska A.. Trends Biotechnol[J], 2002, 20: 305—311
[14]Ying L., Kang E. T., Neoh K. G., et al.. Membr. J. Sci.[J], 2004, 243: 253—262
[15]Wallmersperger T., Kroplin B., Gulch R. W.. Mater.[J], 2004, 36: 411—420
[16]Shahinpoor M.. Smart Mater. Struct.[J], 1994, 3: 367—372
[17]Fragala A., Enos J., LaConti A., et al.. Electrochim. Acta[J], 1972, 17: 1507—1522
[18]Shoenfeld N. A., Grodzinsky A.. J. Biopolymers[J], 1980, 19: 241—262
[19]De Rossi D., Chiarelli P., Buzzigoli G., et al.. Trans. Am. Soc. Artif. Inter. Organs[J], 1986, 17: 157—162
[20]Kwon I. C., Bae Y. H., Kim S. W.. Nature[J], 1991, 354: 291—293
[21]Nanavati C., Fernandez J. M.. Science[J], 1993, 259: 963—965
[22]Eisenberg S. R., Grodzinsky A. J.. J. Membrane Sci.[J], 1984, 19: 173—194
[23]Osada Y., Hasebe M.. Chem. Lett.[J], 1985: 1285—1287
[24]SHANG Jing(尚婧), CHEN Xin(陈新), SHAO Zheng-Zhong(邵正中). Progress in Chemistry(化学进展)[J], 2007, 19(9): 1393—1399
[25]Eisenberg S. R., Grodzinsky A. J.. ASME Journal of Biochemical Engineering[J], 1987, 109: 79—89
[26]Doi M., Matsumoto M., Hirose Y.. Macromolecules[J], 1992, 25: 5504—5511
[27]Li H., Chen J., Lam K. Y.. Biosensors and Bioelectronics[J], 2007, 22: 1622—1641
[28]Lin S. B., Yuan C. H., Ke A. R., et al.. Sensors & Actuator: B Chemical[J], 2008, 134: 281—286
[29]ZHUO Ren-Xi(卓仁喜), ZHANG Xian-Zheng(张先正). Acta Polymerica Sinica(高分子学报)[J], 1998, 41(1): 39—43
[30]JIN Xia-Chao(金霞朝), HUANG Yong-Min(黄永民), ZHOU Yuan(周圆), et al.. Acta Polymerica Sinica(高分子学报)[J], 2007, 50(8): 737—741
[31]Flory P. J.. Principles of Polymer Chemistry[M], New York: Cornell University Press, 1953

Electric-sensitive Properties and Mechanism of P(AMPS-co-BMA) Hydrogels

PDF (PC)

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 0

Recommended Articles

Metrics

Comments