Synthesis and Bioactivity of Salicylic Acid Saccharide Carboxylate

Chem. J. Chinese Universities

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Synthesis and Bioactivity of Salicylic Acid Saccharide Carboxylate

ZANG Hong-Jun¹, LI Zheng-Ming², NI Chang-Chun³, SHEN Zhou³, FAN Zhi-Jin², LIU Xiu-Feng²

1. Tianjin Municipal Key Laboratory of Fiber Modification & Functional Fiber, School of Material Science and Chemistry Engineering, Tianjin Polytechnic University, Tianjin 300160, China;
2. State Key Labortary of Elementoorganic Chemisty, Institute of Elemento-organic Chemistry, Nankai University, Tianjin 300071, China;
3. Shanghai Branch of National Pesticide R & D South Center, Shanghai 200032, China

Received:2005-09-28 Revised:1900-01-01 Online:2006-10-10 Published:2006-10-10
Contact: LI Zheng-Ming

Abstract

Abstract: The plant activators such as salicylic acid and acetosalicylic act as a regulary molecue in plants which can stimulate the biosynthesis of phytoalexin to inhibit the growth of micobial patogens. In order to investigate the synergic effect of the glucose and salicylic acid, ten new glycosyl esters of salicylic acid were synthesized by the reaction of salicylic acid and acetosalicylic acid with acetylated glycosyl bromide. The structures were confirmed by elemental analysis and ¹H NMR. The ¹H NMR spectra showed that they were β-isomer. Bioassay results indicate that several compounds show a better induced activity against pathogen infection than salicylic acid.

Key words: Salicylic acid, Acetosalicylic acid , Acetyl glycosyl esters, Induced resistance, Bioactivity

CLC Number:

O625

TrendMD:

ZANG Hong-Jun¹, LI Zheng-Ming², NI Chang-Chun³, SHEN Zhou³, FAN Zhi-Jin², LIU Xiu-Feng². Synthesis and Bioactivity of Salicylic Acid Saccharide Carboxylate[J]. Chem. J. Chinese Universities, doi: .

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Synthesis and Bioactivity of Salicylic Acid Saccharide Carboxylate

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