Cure Kinetics Study of the Polymerization of N,N,N′N′-Tetrapropargyl-p,p′-Diamino Diphenyl Methane with 1,1′-Bezidomethyl-4,4′-biphenyl

Chem. J. Chinese Universities ›› 2006, Vol. 27 ›› Issue (1): 170.

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Cure Kinetics Study of the Polymerization of N,N,N′N′-Tetrapropargyl-p,p′-Diamino Diphenyl Methane with 1,1′-Bezidomethyl-4,4′-biphenyl

LUO Yong-Hong¹, HU Yan-Hong¹, WAN Li-Qiang¹, XUE Lian¹, ZHOU Wei¹, HUANG Fa-Rong ^1* , SHEN Xue-Ning¹, QI Hui-Min¹, DU Lei ², CHEN Xiang-Bao³

1. Key Laboratory for Ultrafine Materials of Ministry of Education, School of Material Science and Engineering,
East China University of Science and Technology, Shanghai 200237, China; 2. The Eighth Academy of China Aerospace Corporation, Shanghai 200233, China; 3. Beijing Institute of Aeronautical Materials, Beijing 100095, China

Received:2005-01-12 Online:2006-01-10 Published:2006-01-10
Contact: HUANG Fa-Rong ,E-mail: fhuanglab@ecust.edu.cn

Abstract

Abstract:

A novel low temperature curing resin was prepared by the 1,3-dipolar cycloaddition polymerization of N,N,N′,N′-tetrapropargyl-p,p′-diamino diphenyl methane(TPDDM) and 1,1′-bezidomethyl-4,4′-biphenyl(BAMBP) at 70 ℃. The variation of TPDDM with BAMBP of the reactively functional groups during the polymerization was traced by FTIR, the polymerizing reaction of TPDDM with BAMBP and the reaction kinetics were investigated using FTIR and differential scanning calorimetry(DSC) at a variety of heating rates. The kinetic parameters at different temperatures including the reaction order, activation energy and pre-exponential factor were obtained. The apparent reaction order n, activation energy Ea and pre-exponential factor A calculated from FTIR and DSC data were mutually evidential.

Key words: TPDDM; BAMBP; 1,2,3-Polytriazole; Curing kinetics

CLC Number:

O631

TrendMD:

LUO Yong-Hong, HU Yan-Hong, WAN Li-Qiang, XUE Lian, ZHOU Wei, HUANG Fa-Rong, SHEN Xue-Ning, QI Hui-Min, DU Lei, CHEN Xiang-Bao. Cure Kinetics Study of the Polymerization of N,N,N′N′-Tetrapropargyl-p,p′-Diamino Diphenyl Methane with 1,1′-Bezidomethyl-4,4′-biphenyl[J]. Chem. J. Chinese Universities, 2006, 27(1): 170.

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Cure Kinetics Study of the Polymerization of N,N,N′N′-Tetrapropargyl-p,p′-Diamino Diphenyl Methane with 1,1′-Bezidomethyl-4,4′-biphenyl

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