Synthesis, Characterization and Molecular Structure of a Novel Asymmetrical Half-sandwich Binuclear Iron Carborane Complex Cp′2Fe2(CO)3(Se2C2B10H10)

Chem. J. Chinese Universities ›› 2002, Vol. 23 ›› Issue (6): 1077.

• Articles • Previous Articles Next Articles

Synthesis, Characterization and Molecular Structure of a Novel Asymmetrical Half-sandwich Binuclear Iron Carborane Complex Cp′₂Fe₂(CO)₃(Se₂C₂B₁₀H₁₀)

LU Shi-Xiang^1,2, JIN Guo-Xin¹, HU Ning-Hai¹

1. Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China;
2. College of Chemistry, Jinlin University, Changchun 130023, China

Received:2001-04-09 Online:2002-06-24 Published:2002-06-24

Abstract

Abstract: The half sandwich methylcyclopentadienyl iron carbonyl complex reacted with 1,2-dilithium diselenolate carborane Li 2Se₂C₂B₁₀H₁₀ (1) which was produced by the insertion of element Se into 1,2-dilithium carborane to give a half sandwich binuclear iron carborane complex Cp′ 2Fe₂(CO)₃Se₂C₂B₁₀H₁₀ (3). X-ray structural analysis of complex 3 reveals that one of the iron atoms is chiral.

Key words: Carborane, Half-sandwich methylcyclopentadienyl iron carbonyl complex, Asymmetrical structrure, X-ray molecular structure anylysis

CLC Number:

O614.81

TrendMD:

LU Shi-Xiang, JIN Guo-Xin, HU Ning-Hai . Synthesis, Characterization and Molecular Structure of a Novel Asymmetrical Half-sandwich Binuclear Iron Carborane Complex Cp′₂Fe₂(CO)₃(Se₂C₂B₁₀H₁₀)[J]. Chem. J. Chinese Universities, 2002, 23(6): 1077.

[1]	WU Juan, WANG Hongqiang, LIU Xiaoyun, SHI Zhiyuan, QIU Yongqing. Theoretical Study on the Second-order Nonlinear Optical Properties of D-A-D(D') o-Carborane Triads^† [J]. Chem. J. Chinese Universities, 2018, 39(7): 1490.
[2]	LI Rongrong, WANG Hongqiang, WANG Li, WU Juan, QIU Yongqing. Theoretical Study on the Second-order Nonlinear Optical Properties of Diaryl Ammonia(Boron)-π-carborane Ternary Compounds^† [J]. Chem. J. Chinese Universities, 2017, 38(10): 1796.
[3]	FANG Xinyan, WANG Wenyong, WANG Jiao, LI Xiaoqian, SONG Hongjuan, QIU Yongqing. Theoretical Studies on the Structures and Second-order Nonlinear Optical Properties of 12-Vertex Fluorocarborane Molecules^† [J]. Chem. J. Chinese Universities, 2014, 35(11): 2377.
[4]	WANG Jiao, ZHANG Meng-Ying, ZOU Hai-Yan, YU Hai-Ling, WANG Wen-Yong, SONG Hong-Juan, LI Xiao-Qian, QIU Yong-Qing. Theoretical Study on Redox-adjustable Second-order Nonlinear Optical Responses of 12-Vertex [1-R-CB₁₁-Me₁₁]^- Carborane Complexes [J]. Chem. J. Chinese Universities, 2013, 34(12): 2791.
[5]	LI Xiao-Qian, MA Na-Na, LI Xue, ZOU Hai-Yan, SUN Shi-Ling, QIU Yong-Qing. Theoretical Study on Second-order Nonlinear Optical Properties of 12-Vertex Carborane Ni(Ⅱ) Complexes [J]. Chem. J. Chinese Universities, 2013, 34(1): 135.
[6]	LIU Xiao-Dong, YU Yan-Bo, QIU Yong-Qing^*, SUN Shi-Ling, CHEN Hui, SU Zhong-Min, WANG Rong-Shun. DFT Study on Second-order Nonlinear Optical Properties of a Series of 12-Vertex Bis-substituted o-Carborane Derivatives [J]. Chem. J. Chinese Universities, 2008, 29(9): 1816.
[7]	CHEN Bao-Guo^1,2, ZHANG Ming-Yu¹*, ZHAO Yuan-Yuan¹, SUN Chia-Chung¹. Structural and Electronic Properties of 1,2-C2B10H12 Isonitrile Derivatives Used in Boron Neutron Capture Therapy [J]. Chem. J. Chinese Universities, 2007, 28(4): 760.
[8]	KONG Qing-An, JIN Guo-Xin, LIN Yong-Hua . Synthesis and Characterization of Cp^tRh(PMe₃)(Se₂C₂B₁₀H in 16-and 18-Electron Half-sandwich Rhodium Complexes with 1,2-Dichalcogenolate Carborane [J]. Chem. J. Chinese Universities, 2002, 23(3): 410.
[9]	ZHANG Ming-Yu, YU Wei-Zhou, ZHOU Jian-Wei, SUN Chia-Chung . Ab Initio Calculation Study on Vibrational Spectra of Bis (C-p-carboranyl) (C₂B₁₀H₁₁)₂ [J]. Chem. J. Chinese Universities, 1997, 18(8): 1361.
[10]	ZOU Jian-Wei, ZHANG Ming-Yu, YU Wei-Zhou, SUN Chia-Chung. Ab Initio Studies on Directing Effects of Electrophilic Substitution for Closo Icosahedral Carboranes [J]. Chem. J. Chinese Universities, 1997, 18(12): 2012.
[11]	ZHANG Ming-Yu, YU Wei-Zhou, LI Xiao-Tian. Ab Initio Calculations on Ih Symmetry Boron and Carbon Clusters(Ⅱ)─The Electron Structure and Stability for C₁₂B₂₀,C₁₂B₂₀H₃₂ and Its Cations [J]. Chem. J. Chinese Universities, 1994, 15(8): 1214.
[12]	ZHANG Ming-Yu, YU Wei-Zhou, LI Xiao-Tian. Ab Initio Studies on Boron and Carbon Clusters of I_h Symmetry(Ⅰ)──Geometries and Stabilities of B₃₂,C₂B₃₀ and B₃₂H₃₂^2- [J]. Chem. J. Chinese Universities, 1994, 15(5): 754.
[13]	Li Qian-shu, Tang Ao-qing . The Quantum-Chemical Calculation for Structural Rule of Carborancs [J]. Chem. J. Chinese Universities, 1991, 12(1): 69.

Synthesis, Characterization and Molecular Structure of a Novel Asymmetrical Half-sandwich Binuclear Iron Carborane Complex Cp′₂Fe₂(CO)₃(Se₂C₂B₁₀H₁₀)

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 13

Recommended Articles

Metrics

Comments