Studies on the Mechanism of the Initial Dark Oxidation of Ethers

Abstract

Abstract: The contact charge transfer (CCT) complexes of isopropyl ether, phenyl isopropyl ether and benzyl isopropyl ether with O₂were measured. It was found that the oxygenative position of isopropyl ether is different from that of phenyl isopropyl ether and benzyl isopropyl ether due to benzene ring in their structures. In the former the oxygenative position is at the etheroxy bond while in the latter at the benzene ring. The mechanism of the initial dark oxidation of ether was proposed.

Key words: Contact charge transfer(CCT) complex, Ultraviolet absorption spectrum, Dark oxidation mechanism

CLC Number:

O631.3

TrendMD:

ZHU Jun-Min, CAO Wei-Xiao, FENG Xin-De . Studies on the Mechanism of the Initial Dark Oxidation of Ethers[J]. Chem. J. Chinese Universities, 1998, 19(7): 1181.

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Studies on the Mechanism of the Initial Dark Oxidation of Ethers

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