Chem. J. Chinese Universities ›› 1997, Vol. 18 ›› Issue (5): 665.

• Articles •     Next Articles

Synthesis of C60-Pyrrolidine Derivatives by 1,3-Dipolar Cycloaddition of Azomethine Ylides to C60

ZHOU De-Jian1, ZHAO Yi-Lei1, GAN Liang-Bing1, LUO Chu-Ping1, HUANG Chun-Hui1, LU Mu-Jian2, PAN Jinn-Qi2, WU Yi3   

  1. 1. State Key Laboratory of Rare Earth Materials Chemistry and Applications, Peking University, Beijing, 100871;
    2. College of Chemistry and Molecular, Engineering Peking University, Beijing, 100871;
    3. Beijing In.situte of Microchemistry, Beijing, 100091
  • Received:1996-05-23 Online:1997-05-24 Published:1997-05-24

Abstract: Aseries of different substituted azomethine Ylides were prepared through the reaction between sarcosine and different substituted benzoaldehydes, conjugated aldehydes and ketones.Further 1, 3-dipolar cycloaddition of these azomethine Ylides to C60 give rise to a series of new C60-pyrrolidine derivatives.The molecular structures of these compounds were ldent1fied and characterized by 1HNMR, 13CNMR, FDMS, FT-IRand UV-Vis spectro-scopies.

Key words: C60-Pyrrolidine derivative, Sarcosine, Azomethine ylides, 1,3-Dipolar cycloaddition

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