Chem. J. Chinese Universities ›› 1997, Vol. 18 ›› Issue (2): 238.
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GU Wen-Xiang1, WANG Hong-Xing2, PAN Yin-Ming2, HUAN Zhen-Wei2, CHENG Jin-Pei2
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Abstract: The reaction of dichlorocarbene with tetraphenylcyclone (1) resulted in carbon monoxide and gem-dichloro compound (3) together with dichlorooxirane (4) and adduct (5).The aromatic structure of carbonyl Ylide and its twist geometry led to deoxygenation to be the main reaction pathway.
Key words: Halocarbene, Carbonyl Ylide, Deoxygenation
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GU Wen-Xiang, WANG Hong-Xing, PAN Yin-Ming, HUAN Zhen-Wei, CHENG Jin-Pei. Studies on Mechanism of Reaction of Dichlorocarbene with Tetraphenylcyclopentadienone[J]. Chem. J. Chinese Universities, 1997, 18(2): 238.
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http://www.cjcu.jlu.edu.cn/EN/Y1997/V18/I2/238