Chem. J. Chinese Universities ›› 1993, Vol. 14 ›› Issue (9): 1280.

• Articles • Previous Articles     Next Articles

Studies on the Determination of Infinite Dilution Activity Coefficients of Acetone-Cycloalkane Systems by Gas Stripping Method

BAO Jian-Bin, HANG Lai-Lai, LING Yue-Ping, CHEN Geng-Hua, HAN Shi-Jun   

  1. Department of Chemistry, Zhejiang University, Hangzhou, 310027
  • Received:1992-11-07 Revised:1993-04-14 Online:1993-09-24 Published:1993-09-24

Abstract: Apre-saturator would be added for the gas stripping method to maintain the amounts of the solvent if it was a high-volatile substance.The infinite dilution activity coefficients of three acetone-cycloalkane systems:acetone-methyl cyclopentane, acetone-cyclohexane, acetone-methyl cyclohexane have been determined in the 298.2-318.2 Ktemperature region.Linear dependence of Inγ on1/Tis found for all systems, and the temperature parameters are in the order:cyclohexane<methyl cyclopentane<methyl cyclohexane.Furthermore, the experimental results are used to predict the whole range VLE.The results show that Wilson equation gives the best fit to literature data.

Key words: Acetone-cycloalkane system, Infinite dilution activity coefficient, Gas stripping method

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