Chem. J. Chinese Universities ›› 1991, Vol. 12 ›› Issue (4): 548.
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Wang Yong-wei, Zhang Hua-lin
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Abstract: The kinetics of the metal exchange reaction between o-hydroxybenzylamine-N,N,O-tri-acetic acid(H3L) complex of molybdenum (Ⅵ) and cupric ion has been studied by means of stopped-flow technique over the pHrange of 3. 3l-4.16 at 10℃, I=0. 5 mol/L(NaCl). The variation of the pseudo-first order rate constant kobs with [H+] and CCu indicates a SN1 IP mechanism and the following rate equation and reaction scheme were derived on it:(这里有图片199104-500-3.gif).
Key words: Molybdenum(Ⅵ), o-Hydroxybenzylamine-N,N,O-triacetic acid, Exchange reaction kinetics
TrendMD:
Wang Yong-wei, Zhang Hua-lin . Studies on the Kinetics of the Metal Exchange Reaction Between o-Hydroxybenzylamine-N,N,O-Triacetic Acid Complex of Mo (Ⅵ) and Cu2+[J]. Chem. J. Chinese Universities, 1991, 12(4): 548.
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http://www.cjcu.jlu.edu.cn/EN/Y1991/V12/I4/548
