Chem. J. Chinese Universities ›› 1987, Vol. 8 ›› Issue (1): 73.

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Activity Coefficients of HCl in the System HCl-KCl-PrOH-H2O from 5 to 45℃

Li Zijun, Yang Jiazhen, Liang Chunyu   

  1. Department of Chemistry, Liaoning University, Shenyang
  • Received:1985-08-30 Online:1987-01-24 Published:1987-01-24

Abstract: This paper reports that emf of cellPt,H2(latm) |HCl(mA),KCl(mB),RrOH(x),H2O(1-x) | AgCl-Ag(A) have been made at 5-45℃ regions and x= 0.02,0.05,0.08 and 0.12, where x is molar fraction of PrOH in mixed solvents.The results show that HCl also obeys Harned' s Rule and logarithms of activity coefficients of HCl are a linear function for temperature.Relative patial molar enthalpy of HCl have been discussed.

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