Chem. J. Chinese Universities ›› 1986, Vol. 7 ›› Issue (2): 137.
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Li Liangzhu, Zhang Xusheng
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Abstract: Intramolecular alkylation of α-4-chlorobutyrylcyclopentanone and α-4-chlorobu-tyrylcyclohexanone easily occurs at oxygen to form α-furanidin-2-ylenecyclopentanone and α-furanidin-2-ylenecyclohexanone, respectively, but the corresponding C-alkyla-tion does not take place. The C-alkylation of the related α-acetylcycloketones also hardly takes place and they are converted to the corresponding keto-esters with EtONa-EtOH.
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Li Liangzhu, Zhang Xusheng . The Primary Attempt of α-Acylcycloketone Alkylation and the Synthesis of α-Furanidin-2-Ylenecyclo-Pentanone and Hexanone[J]. Chem. J. Chinese Universities, 1986, 7(2): 137.
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