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Chem. J. Chinese Universities ›› 1984, Vol. 5 ›› Issue (4): 573.

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A Kinetic Study of Alternating Copolymerization of Butadiene and Propylene Based on Vanadium-Aluminium Catalyst (Ⅲ)——Kinetic Parameters of Alternating Propagation and the Partial Reaction Orders of Two Monomers

Jiao Shuke, Huang Baochen   

  1. Department of Polymer Science, Beijing Institute of Chemical Technology, Beijing
  • Received:1982-06-03 Online:1984-10-24 Published:1984-10-24

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Abstract: On the basis of analysis of two monomers alternating propagation, the rate constants, i. e. kB-P and kP-B, reactivity ratio and activation energy were determined according to the hypothesis of steady-state. In addition, the partial reaction orders for two monomers were obtained through treating the data of polymerization rate by graphic method.

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