Chem. J. Chinese Universities ›› 1984, Vol. 5 ›› Issue (2): 215.

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ELECTROCHEMICAL BEHAVIOUR OF TITANIUM SUBCHLORIDES IN NaCl-KCl AND LiCl-KCl MELTS

Yang Qiqin, Liu Guankun   

  1. Department of Chemistry, Zhongshan University, Guangzhou
  • Received:1982-08-09 Online:1984-04-24 Published:1984-04-24

Abstract: The electrode reaction steps of Ti(Ⅲ) and Ti(Ⅱ) in NaCl-KCl and LiCl-KCl eutectic melts are investigated with the aid of chronopotentio-metry and linear sweep voltammetry. The diffusion coefficients of Ti (Ⅲ) and Ti(Ⅱ)at various temperatures and the diffusion activation energies are calculated.The effects of some factors, especially of the temperature, on the. electrocrystallization of titanium are also discussed.

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