Chem. J. Chinese Universities ›› 2012, Vol. 33 ›› Issue (07): 1523.doi: 10.3969/j.issn.0251-0790.2012.07.029

• Physical Chemistry • Previous Articles     Next Articles

Volumetric Properties of Binary Systems of n-Butanol or n-Pentanol+JP-10

XIAO Juan, GUO Yong-Sheng, YANG Yu-Zhong, GONG Xian-Jie, FANG Wen-Jun, LIN Rui-Sen   

  1. Department of Chemistry, Zhejiang University, Hangzhou 310058, China
  • Received:2011-11-15 Online:2012-07-10 Published:2012-07-10

Abstract: The kinematic viscosities and densities of the binary mixtures of n-butanol/n-pentanol+JP-10(exo-tricycle[5.2.1.02.6]decane, C10H16) were determined at 298.15 K via Ubbelohde viscometer and Anton PaarDMA55 vibrating-tube digital densimeter. Thermodynamic functions of activation of the binary systems were calculated according to the absolute rate theory approach of Eyring, which indicate ΔH0≠ plays a major role. Excess molar volumes, excess partial molar volumes, apparent molar volumes and partial molar volumes were calculated based on the densities data. The results indicate that VmE of the binary systems are positive.

Key words: JP-10(exo-tricycledecane), n-Butanol, n-Pentanol, Binary system, Volumetric property

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