Structural Studies on Partially Disordered Layer Lattice of Zirconium Pillared Montmorillonite

Abstract

Abstract: The structure of pillared montmorillonite is the partially disordered layer lattice.Its basal spacings can be expanded to many possible values with different probabilities depending on the type and structure of the pillars.If a formula describing the X-ray diffraction intensity of partially disordered layer lattice as a function of basal spacings and the corresponding probabilities is computationally simulated with the experimental XRDpattern, the basal spacings and probabilities can thus be obtained.In this paper, zirconium pillared montmorillonite samples were prepared.The simulated results show that the basal spacings are expanded to 2.55 nm, 2.10 nm and 1.26 nm with probabilities of 35%, 2.7% and 38% corresponding to [Zr₄(OH)₈(H₂O)₁₆]⁸⁺, [Zr₃(OH)₄(H₂O)₅]⁸⁺ ions together with some adsorbed water molecules and H₂Oas the main pillaring species in the interlamellar regions, respectively.The experimental results obtained from CBC, ICPetc.are applied to calculating the distribution of the pillars in the interlayer zone.The fashion of the connection between pillars and unite layers is also given.Subsequently, a three-dimensional statistical structural model is built up.The agreement of the pore-volume between the theoretical calculation and experimental result verifies the rationality of the structural model.Therefore, the basal spacing characterized by d001 which is calculated from Bragg e-quation is not exact actually.

Key words: Montmorillonite, Partially disordered layer lattice, Structural model, Zirconium

TrendMD:

WANG Jun, WANG Lian-Bo, JIANG Qing, LI Hong, XIANG Si-Fen, LIN Bing-Xiong . Structural Studies on Partially Disordered Layer Lattice of Zirconium Pillared Montmorillonite[J]. Chem. J. Chinese Universities, 1993, 14(7): 902.

[1]	XU Huan, KE Lyu, TANG Mengke, SHANG Han, XU Wenxuan, ZHANG Zilin, FU Yanan, HAN Guangdong, CUI Jinsheng, YANG Haoran, GAO Jiefeng, ZHANG Shenghui, HE Xinjian. In⁃situ Liquid Exfoliation of Montmorillonite Nanosheets in Poly（lactic acid） to Resist Oxygen Permeation [J]. Chem. J. Chinese Universities, 2022, 43(11): 20220316.
[2]	LI Wen, QIAO Junyi, LIU Xinyao, LIU Yunling. Zirconium-based Metal-Organic Framework with Naphthalene for Fluorescent Detection of Nitroaromatic Explosives in Water [J]. Chem. J. Chinese Universities, 2022, 43(1): 20210654.
[3]	LI Zhanfeng, LIU Benxue, LIU Xiaochan, WANG Xinqiang, ZHANG Jing, YU Shimo, ZHAO Xinfu, ZHANG Xin’en, YI Xibin. Mechanism of the Removal of Acetylacetone Ligands in Zirconia Wet Gel and Fabrication of Zirconia Aerogel Composites [J]. Chem. J. Chinese Universities, 2021, 42(9): 2904.
[4]	ZHANG Jihua,WANG Chao,ZAO Weitao,LI Li,LIU Xiaoyan,YANG Yuan,WANG Hao. Preparation of High-performance Montmorillonite/hydrogenated Butadiene-acrylonitrile Rubber by Using Electrostatic Interfaces [J]. Chem. J. Chinese Universities, 2020, 41(4): 803.
[5]	ZOU Xiaochuan,WANG Yue,WANG Cun,HU Shiwen,SHI Kaiyun. Synthesis of Amine Functionalized ZPS-PVPA Supported Chiral Mn^Ⅲ(salen) and Asymmetric Catalytic Olefin Epoxidation^† [J]. Chem. J. Chinese Universities, 2019, 40(7): 1488.
[6]	LUAN Jingde, LIU Yawei, ZHANG Chengyu, KE Xin. Synchronization Capture of Zn²⁺ and p-Nitrophenyl Phenol on Montmorillonite Composites^† [J]. Chem. J. Chinese Universities, 2018, 39(2): 270.
[7]	LUO Huayong,RONG Hongwei,ZENG Xueyang,WANG Randeng,CHU Zhaorui. Performance of Phosphorus Sorption on Thermosensitive Zirconium Alginate Hydrogel Beads with Full-interpenetrating Network^† [J]. Chem. J. Chinese Universities, 2018, 39(10): 2289.
[8]	ZHANG Yixin, WANG Mengxue, ZHANG Zheyuan, MI Puke, WANG Tinglan. Polyethylene-b-poly(ethylene/1-octene) Block Copolymer Prepared via Novel Dinuclear FI/Nickel(Ⅱ) α-Diiminecatalytic Systems [J]. Chem. J. Chinese Universities, 2017, 38(8): 1497.
[9]	LI Tingting, ZHAO Lele, WANG Ruili, ZHANG Shuqiu. Preparation and in vitro Release of Ketoprofen/acid-montmorillonite^† [J]. Chem. J. Chinese Universities, 2017, 38(5): 722.
[10]	LI Qintao, SUN Wen, ZHANG Qin, PAN Huifen, XU Jie. In Situ Crystallized Zirconium Phenylphosphonate Films on the Copper Mesh and Its Application in Oil/water Separation^† [J]. Chem. J. Chinese Universities, 2017, 38(3): 464.
[11]	LI Xingjian,JU Yunpeng,CHANG Degong,ZHANG Yiheng. Preparation and Properties of Flame Retardant Waterborne Polyurethane Nanocomposites via Click Reaction^† [J]. Chem. J. Chinese Universities, 2016, 37(8): 1580.
[12]	QIN Yichao, YE Jian, JIANG Binbo, WANG Jingdai, YANG Yongrong. Ethylene Oligomerization and Friedel-Crafts Alkylation Tandem Action Catalyzed by Aryloxy Zirconium Catalysts^† [J]. Chem. J. Chinese Universities, 2015, 36(9): 1825.
[13]	LIU Wenjin, WANG Hongning, CHEN Ruoyu. Synthesis of Mixed Alumina Silica Pillared Zirconium Phosphate and Its Catalytic Performance in Epoxidation of Soyate^† [J]. Chem. J. Chinese Universities, 2015, 36(12): 2550.
[14]	WANG Xue-Yan, HUA Wei-Ming, YUE Ying-Hong, GAO Zi. Porous Phosphate Heterostructure Materials as Green Catalysts in Prins Condensation [J]. Chem. J. Chinese Universities, 2013, 34(8): 1913.
[15]	RAN Shi-Ya, XU Yuan-Yuan, GUO Zheng-Hong, FANG Zheng-Ping. Synergistic Flame Retardant of Acid or Alkali-treated Montmrillonite/Phosphate Flame Retardant in PC/ABS Blends [J]. Chem. J. Chinese Universities, 2013, 34(2): 467.

Structural Studies on Partially Disordered Layer Lattice of Zirconium Pillared Montmorillonite

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments