Chem. J. Chinese Universities

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Synthesis and Characterization of High-pressure Metamorphic SiO2 Minerals

SUN Jing-Shu1, LIU Xiao-Mei1, XU Da-Peng1, SU Wen-Hui1,2,3, ZHANG Guo-Qiang1, WANG De-Yong1, WANG De1   

    1. College of Physics, Jilin University, Changchun 130023, China;
    2. Center for Condensed Matter Science and Technology, Harbin Institute of
      Technology, Harbin 150001, China;
    3. International Center for Materials Physics, Chinese Academy of Sciences,
      Shenyang 110015, China
  • Received:2005-12-14 Revised:1900-01-01 Online:2006-11-10 Published:2006-11-10
  • Contact: LIU Xiao-Mei

Abstract: We suggest a new laboratory method for synthesizing coesite in the earth's crust by considering the similarity characteristics of local collisions and shearing strength between the earth's plates and high energy mechanical ball milling(MBM), combining the high-energy MBM and high static pressure and high temperature technique, and using mixtures of α-quartz and graphite as the initial material. The nanometer amorphous mixture of α-quartz and graphite was prepared by high-energy MBM. The lowest pressure and temperature for synthesizing coesite are 3.7 GPa, 970 K. The Raman spectrum of synthetic coesite possessed ten peaks located at 120, 152, 179, 206, 270, 329, 357, 428, 467 and 521 cm-1. The obtained spectrum is coesite Raman spectrum with the most peaks among published results. The author attempts to look for useful information about the mineral circumstance of coesite in the Earth'surface and the mechanism of the ultrahigh-pressure metamorphism.

Key words: α-Quartz-graphite, Coesite, High-energy mechanical ball milling, High temperature and high pressure

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