CJCU

Chem. J. Chinese Universities ›› 1996, Vol. 17 ›› Issue (5): 820.

• Articles • Previous Articles     Next Articles

The Solution Properties of Phenolphthalein Poly (arylether sulfone)(Ⅰ) ──The Solubility Behavior and Determination of M-H Equations

BO Shu-Qin, YANG Guo-Jun, PAN Hai-Yan, HU Hui-Zhen, CHEN Tian-Lu   

  1. Polymer Physics Laboratory, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022
  • Received:1995-05-24 Online:1996-05-24 Published:1996-05-24

PDF (PC)

Abstract: Aseries of narrow molecular weight distribution fractions of phenolphthalein polyarylether sulfone(PES-C)had been prepared.The Mw of these fractions were determined by conventional light scattering method.The[η]and the Huggins slope constant k' in DMF, CHCl3 and 1,2-dichloroethane were also determined.The Huggins constants are greater than 0.5 in all of these solvents showing a special solubility behvior .The Mark-Houwink equations of PES-Cin these solvents at 25℃ are [η]=2.79× 10-2Mw0.615(DMF);[η]=3.96× 10-2Mw0.58(CHCl3); [η]=7.40× 10-2Mw0.52(CH2ClCH2Cl).

Key words: Solution property of polymer, Mark-Houwink equation, Phenolphthalein poly (arylether sulfone)

TrendMD: