Methane Storage Performace of Self-activated Seaweed-based Carbon Materials†

doi:10.7503/cjcu20180224

Abstract

Abstract:

Two types of carbon material were prepared by self-activation using the seaweeds Hizikia fusifarme(Sar) and Laminaria japonica(Lam) as raw materials. The methane storage capacity of SarCW-900-HF and LamCW-900-HF are up to 272 mg/g(mass fraction 21.3%) and 246 mg/g(mass fraction 19.4%) at room temperature and pressure of 3.5 MPa. The specific surface area of the two materials are 812 and 671 m²/g, and pore volume are 0.45 and 0.44 cm³/g, respectively. The peak of pore distribution is at 1.1 nm. After tableting under pressure of 20 MPa, the methane adsorption volume ratio reached 274 and 449 cm³(STP)/cm³, beyond the DOE’s target of 263 cm³(STP)/cm³.

Key words: Hizikia fusifarme(Sar), Laminaria japonica(Lam), Self-activation, High pressure methane storage

CLC Number:

O613.71

TrendMD:

WANG Yun,BEN Teng. Methane Storage Performace of Self-activated Seaweed-based Carbon Materials^†[J]. Chem. J. Chinese Universities, 2018, 39(10): 2143.

Figures/Tables 14

Scheme 1 Schematic of the pyrolysis process of Hizikia fusifarme and Laminaria japonica

Fig.1 N2 sorption isotherms of different carbonized biomasses(A) and pore size distribution of SarCW-900-HF(B) and LamCW-900-HF(C)a. SarCW-900-HF; b. SarCW-850-HF; c. LamCW-900-HF; d. SarCW-950-HF; e. carbonized Walnut peel;f. LamCW-850-HF; g. LamCW-950-HF; h. carbonized passiflora edulia sims peel; i. Bentonite.

Fig.2 SEM images of Sar(A—E), Lam(F—J), SarCW-900-HF(K, L), LamCW-900-HF(O, P), TEM images of SarCW-900-HF(M, N) and LamCW-900-HF(Q, R)Insets of (N) and (R) are the SAED of the sample.

Fig.3 EDS of samples SarCW-900-HF(A) and LamCW-900-HF(B)

Fig.4 XPS of SarCW-900-HF(A) and LamCW-900-HF(B)

Fig.5 XRD patterns of SarCW-900-HF(A) and LamCW-900-HF(B)

Fig.6 Raman spectra of SarCW-900-HF(A) and LamCW-900-HF(B)

Fig.7 TGA curves of SarCW-900-HF(A) and LamCW-900-HF(B) in air

Fig.8 Adsorption-desorption isotherms(A, B) and Qst(C, D) of SarCW-900-HF(A, C) and LamCW-900-HF(B, D)

Fig.9 High pressure methane storage curves of SarCW-900-HF(A) and LamCW-900-HF(B)

Table 1 Summary of methane storage capacities of some porpus materials

Material		Surface area/ (m²·g^-1)		Pore volume/ (cm³·g^-1)		Condition				CH₄ storage capacity (mass ratio,%)		Excess CH₄ uptake/ (cm³·cm^-3)		Heat of adsorption/ (kJ·mol^-1)		Ref.
Material		Surface area/ (m²·g^-1)		Pore volume/ (cm³·g^-1)		p/MPa		T/K		CH₄ storage capacity (mass ratio,%)		Excess CH₄ uptake/ (cm³·cm^-3)		Heat of adsorption/ (kJ·mol^-1)		Ref.
Porous	COF-102		3620		1.55		3.5		298		15.8		120		8.6		[20]
polymers	COF-103		3530		1.54		3.5		298		14.9		152		9.5		[20]
	HCP-1		1904		0.54		1.5		298		6.4						[21]
	HCP-4		1366		0.55		3.6		298		8.1						[21]
	PIM-1		850		0.349		1.5		293		3.8						[22]
	PPN-3		2840		1.7		3.5		295		12.2				15.2		[23]
	PPN-4		6461		3.04		5.5		295		21.5						[24]
MOFs	Cu₂(sbtc)[PCN-11]		1931		0.91		2.5		298		14.0		171		14.6		[25]
	Ni(dhtp)[NiMOF-74,CPO-27-Ni]		1027		0.54		3.5		298		11.9		206		21.5—22		[25]
	Zn₄O(bdc)₃[MOF-5]		1870				3.6				13.5		110		12.2		[25]
	LIFM-82		1624		0.71		3.5		298		15.2		196		17.5		[26]
	MOF-905		3490		1.34		3.5		298		18.8		145		11.7		[27]
	HKUST-1		1850		0.78		3.5		298		18.4		227		17.0		[28]
	NU-125		3120		1.29		3.5		298		16.5		182		15.1		[29]
	PCN-14		2000		0.829		3.5		298		17.4		202		17.6		[30]
	UTSA-76		2820		1.06		3.5		298		15.4		211		15.4		[31]
	UTSA-20		1620				3.5		298		18.1		184				[32]
	NOTT-102		3342		1.268		3.5		298		16.5		181		16.0		[33]
	NOTT-103		2958		1.157		3.5		300		15.6		193		15.9		[33]
	MAF-38		2022		0.808		3.5		298		14.1		226		21.6		[34]
	ZJU-35		2899		1.156		3.5		300		14.4		177				[35]
	MIL-100(Cr)		1900		1.1		3.5				11.7		144		19		[36]
Zeolites	CaX				0.36		3.2		298		7.5				24.68		[37]
Porous	CMK-3		950		0.87		3.5		298		7.5				19.78		[38]
carbon	K-PAF-1-750		2926				3.5		298		17.1				17.9		[39]
material	Maxsorb A		3100				4.0		298		16.4		152				[40]
	KUA31752		3355				4.0		298		15.6		155				[40]
	PC		1220		0.47		2.0		298		10.2		141				[40]
	Saran A carbon 36X		1650				3.2		298		11.5						[41]
	KF-1500		1500				3.2		298		7.6						[41]
	UlaC-950-HF		1476		0.61		3.5		298		17		232		22.4		[42]

Fig.10 High pressure methane storage curves of SarCWP-900-HF(A) and LamCWP-900-HF(B)

Scheme 2 Schematic illustration of formation of carbon materials and methane molecules adsorbed in SarCWP-900-HF and LamCWP-900-HF

Fig.11 Breakthrough curves of LamCW-900-HF for CO2/H2/He(A—C), N2/CO2/He(D—F) and CH4/N2/He(G—I) mixture with ratio of 1:1:2 at 299 K(A), (D), (G): 100 kPa; (B), (E), (H): 200 kPa; (C), (F), (I): 300 kPa.

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