Chem. J. Chinese Universities ›› 1989, Vol. 10 ›› Issue (1): 104.
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Shao Yuanhua, Yuan Haibe, Li Peibiao, Zhao Zaofan
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Abstract: The electroactive system of ethyl violet-perchlorate for perchlorate electrode was studied by Current scan polarography and chronopotentiometry. The results showed that the transfer process of perchlorate ion across the interface of W/DCE is reversible. The response mechanism of perchlorate electrode was verified as a Nernstian response. The standard potential and standard transfer free energy of perchlorate ion are ΔOWΦ0=-0.12V and ΔGtr0W-O=-11.58kJ·mol.
Key words: Ethyl violet-perch lorate, Electrochemistry of charge transfer
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Shao Yuanhua, Yuan Haibe, Li Peibiao, Zhao Zaofan . Study on Charge Transfer of Ethyl Violet-Perchlorate Ion Pair System Across the Interface of Water/1,2-Dichloroethane[J]. Chem. J. Chinese Universities, 1989, 10(1): 104.
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