Synthesis of Long Aliphatic Carbochain Porphyrins and Their LB Films and Study on Their Gas Sensitivity

Abstract

Abstract: Tetranicotinamidephenyl porphyrin(TNAPP) reacts with n-C₁₆H₃₃Br and n-C₁₂H₂₅ Br, respectively to yield the products tetra (N-hexadecyl nicotinamide phenyl) porphyrin bromide (THNAPPBr) and tetra-(N-dodecylnicotinamide phenyl) porphyrin bromide.Its cobalt complex and zinc complex are also prepared.Those porphyrins and metal porphyrins have good film-forming properties.The gas sensitivity studies show that the six kinds of porphyrins are sensitive to NH₃ and has a fine selectivity.

Key words: Porphyrin, LB film, Gas sensitivity

TrendMD:

LIU Yu-Wen, ZHAO Yu-E, WANG Li-Bo, WANG Run-Wei, LIANG Hong-Bin, ZHU Hao, CAO Xi-Zhang. Synthesis of Long Aliphatic Carbochain Porphyrins and Their LB Films and Study on Their Gas Sensitivity[J]. Chem. J. Chinese Universities, 1997, 18(5): 682.

[1]	QIU Liqi, YAO Xiangyang, HE Liangnian. Visible-light-driven Selective Reduction of Carbon Dioxide Catalyzed by Earth-abundant Metalloporphyrin Complexes [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220064.
[2]	YU Bin, CHEN Xiaoyan, ZHAO Yue, CHEN Weichang, XIAO Xinyan, LIU Haiyang. Graphene Oxide-based Cobalt Porphyrin Composites for Electrocatalytic Hydrogen Evolution Reaction [J]. Chem. J. Chinese Universities, 2022, 43(2): 20210549.
[3]	SUN Hao, GONG Jie, YANG Yan, WANG Xinqing, CHEN Huidong. Synthesis of Three-dimensional Ordered In₂O₃ Nanowire Arrays and the Effect of Nanostructure Order on Gas Sensitivity [J]. Chem. J. Chinese Universities, 2021, 42(6): 1730.
[4]	ZHU Qichen, XIONG Ming, TAO Siyu, TANG Siwei, REN Qizhi. Effect of Light Source on the Photocatalytic Performance of Dihydroxynaphthalene by Water-soluble Sulfonated Porphyrins [J]. Chem. J. Chinese Universities, 2021, 42(6): 1933.
[5]	MA Zihui, WANG Mengyan, CAO Hongyu, TANG Qian, WANG Lihao, ZHENG Xuefang. Transient Absorption and Decay Kinetic Properties of Photo-excited Metal Coordinated Tetraphenylporphyrin [J]. Chem. J. Chinese Universities, 2021, 42(3): 767.
[6]	XIE Xingyu, ZHAO Yaxiang, ZHAO Lizhi, LI Rishun, WU Dihao, YE Hui, XIN Qingping, LI Hong, ZHANG Yuzhong. Colorimetric Detection Method for H₂O₂ Based on Two-dimensional Metal-organic Frameworks of Metalloporphyrin [J]. Chem. J. Chinese Universities, 2020, 41(8): 1776.
[7]	CAO Hongyu,MA Zihui,ZHANG Wenqiong,TANG Qian,LI Ruyu,ZHENG Xuefang. Structures and Electronic Absorption Spectra of N/Neo-Confused, Doubly N-Confused and Neo-Confused N-Confused Porphyrin Isomers ^† [J]. Chem. J. Chinese Universities, 2020, 41(2): 341.
[8]	HE Wenli, CHEN Meng, QIAN Dongjin. Pd(Ⅱ)-Directed Layer-by-layer Assembly of Multiporphyrin Arrays on Silica Nanoparticle Surfaces for Photocurrent Generation and Photochromism of Viologens^† [J]. Chem. J. Chinese Universities, 2017, 38(9): 1654.
[9]	SUN Kaifang, CAI Cheng, HOU Zongsheng, WANG Ying, REN Qizhi. Synthesis, Characterization and Catalytic Properties of Series of Water-soluble Sulfonated Porphyrins^† [J]. Chem. J. Chinese Universities, 2017, 38(7): 1117.
[10]	SHI Lei, YANG Wencong, ZENG Shuying, MO Tingting, ZHANG Zhao, CAO Manli, LIU Haiyang. DNA-binding and Anti-tumor Activities of Cobalt Corrole Complexes^† [J]. Chem. J. Chinese Universities, 2016, 37(6): 1059.
[11]	HU Yiping, SHAN Duoliang, LU Xiaoquan. Nonenzyme Sensor Based on Metal Organic Frameworks/Porphyrin/Multiwalled Carbon Nanotubes for Detection of Glucose^† [J]. Chem. J. Chinese Universities, 2016, 37(6): 1082.
[12]	XU Yonghong, HUO Danqun, FA Huanbao, YANG Mei, HOU Changjun. Sensor Array Based on MTPP-AuNPs Compounds for Fast Identification of Organic Small Molecules in Exhaled Breath of Lung Cancer Patients^† [J]. Chem. J. Chinese Universities, 2015, 36(2): 241.
[13]	WANG Tianyang, HU Xiaoxia, SUN Haiya, GUO Jianfeng, LIU Dongzhi, LI Wei, WANG Lichang, ZHOU Xueqin. Photophysical Processes in a Novel Porphyrin-perylene Metallosupramolecule with a Long-lived Triplet State^† [J]. Chem. J. Chinese Universities, 2014, 35(8): 1753.
[14]	YUAN Wei, REN Qingjiang, SUN Hengda, LI Hui, CHENG Yanxiang, MA Dongge. Effect of Peripheral Substituents on Luminescent Properties of the Porphyrin Platinum(Ⅱ) Complexes^† [J]. Chem. J. Chinese Universities, 2014, 35(6): 1229.
[15]	GONG Jian, CAO Hongyu, LI Shenmin, TANG Qian, YANG Yanjie, ZHENG Xuefang. Theoritical Studies on the Structure and Absorption Spectra of Neo-Confused Metal Porphyrin^† [J]. Chem. J. Chinese Universities, 2014, 35(6): 1267.

Synthesis of Long Aliphatic Carbochain Porphyrins and Their LB Films and Study on Their Gas Sensitivity

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments