Poly(methyl methacrylate)/TiO2 Hybrid Polymer Materials Prepared by the Sol-Gel Process

Abstract

Abstract: In this paper, the PMMA/TiO₂ hybrid polymeric materials were prepared by the sol-gel process.In order to introduce the chemical bond between the organic polymer chain and inorganic network in the hybrid, the trimethoxysilyl functional group was introduced on the polymer side chain by copolymerization with 3-(trimethoxysilyl) propyl methacrylate (MSMA).The result of solvent extraction shows that the gel content in the hybrids with the presence of chemical bond through the reaction of MSMAwith titanium(IV) butoxide is much higher.The chemical structure of the hybrid was analyzed by the FTIR, and the effect of inorganic content on the properties of materials were investigated by TGAand DSC.

Key words: Sol-gel process, Hybrid polymeric material, PMMA, Titanium(Ⅳ) butoxide

TrendMD:

HUANG Zhi-Hua, QIU Kun-Yuan. Poly(methyl methacrylate)/TiO₂ Hybrid Polymer Materials Prepared by the Sol-Gel Process[J]. Chem. J. Chinese Universities, 1997, 18(5): 803.

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Poly(methyl methacrylate)/TiO₂ Hybrid Polymer Materials Prepared by the Sol-Gel Process

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