金属锂负极溶剂化结构调控的研究进展
张硕, 丁俊凡, 许睿, 黄佳琦

Progress on the Solvation Structure Regulation of Li Ion for Stable Lithium Metal Anode
ZHANG Shuo, DING Junfan, XU Rui, HUANG Jiaqi
Fig.2 Schematic of the effect of FEC additives on a Li metal anode(A) [ 63], the calculated total coordination number for Li + in LiPF6 in EC with 0, 5%, 10% FEC(B), the representative solvation structures taken from molecular dynamics(MD) simulation snapshots of 1 mol/L LiPF6 in EC(C) and 1 mol/L LiPF6 in EC with 10% FEC(D) [ 64], snapshots of the MD simulation boxes of LiFSI/LiNO3 and LiFSI electrolyte(top panel), schematics of the solvation structure of Li ions in corresponding electrolyte(bottom panel)(E) [ 65] and schematic illustration of the EDL principle in screening reactants to preferentially construct the SEI(F) [ 60]
(A) Copyright 2017, John Wiley and Sons; (B—D) Copyright 2019, Elsevier; (E) Copyright 2019, American Chemical Society; (F) Copyright 2021, John Wiley and Sons.