非热解共价有机聚合物基氧还原电催化材料

鲍春竹, 向中华

Pyrolysis-free Strategy of Covalent Organic Polymers-based Oxygen Reduction Electrocatalytic Materials

BAO Chunzhu, XIANG Zhonghua

Fig.3 Volcano profiles of limiting potential(U) vs. ΔGOOH* for the 2e and 4e ORR processes of TM3(HITP)2 monolayers, the optimal limiting potentials indicated by the dash⁃dot lines(A)[41], schematic diagram of the synthesis(B)[49], optimized structure of (FePcZnPor)2 and (ZnPcFePor)2 moieties as the minimum repeating units for FePcZnPor⁃CMP and ZnPcFePor⁃CMP, respectively(C), schematic valence shell electronic structure of the Fe ions in (FePcZnPor)2 and (ZnPcFePor)2(D)[50] （A） Copyright 2020， American Chemical Society； （B） Copyright 2018， the Royal Society of Chemistry； （C， D） Copyright 2018， the Royal Society of Chemistry.