非贵金属催化剂在羟甲基糠醛电氧化增值中的应用

杜磊, 刘兆清

Non-precious Metal Catalysts for Electro-oxidation Upgrading of 5-Hydroxymethy Furfural

DU Lei, LIU Zhaoqing

Fig.4 Morphological features of Ni2P NPA/NF and conversation of FDCA[50] （A） XRD pattern of Ni2P NPA/NF with the corresponding standard patterns of Ni2P and Ni； （B， C） SEM images of Ni2P NPA/NF with different magnifications； （D） SEM and the corresponding elemental mapping images of Ni2P NPA/NF； （E） LSV curves of Ni2P NPA/NF at a scan rate of 2 mV/s in 1.0 mol/L KOH with and without 10 mmol/L HMF； （F） conversion and yield（%） changes of HMF and its oxidation products during the electrochemical oxidation of HMF at 1.423 V（vs. RHE） in 1.0 mol/L KOH with 10 mmol/L HMF； （G） faradaic efficiencies of Ni2P NPA/NF for FDCA production under three successive electrolysis cycles. Copyright 2016， Wiley-VCH GmbH.